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Azula was not power hungry
A common misconception about Azula is that she was power hungry. But she wasn’t. Everything she did, she did for her father and for the Fire Nation. When she conquered Ba Sing Se, she said, “The Fire Nation has conquered Ba Sing Se” not “I have conquered Ba Sing Se.” She categorized it as a group effort. She definitely thought that she’d make a better Fire Lord than Zuko, but she didn’t actually want to be Fire Lord. If she did, she wouldn’t have brought Zuko home as a hero instead of as a prisoner. Azula seemed perfectly okay with Zuko being the new heir to the throne. All Azula desperately wanted was her father’s approval and affection, and she also was terrified of ending up like Zuko (the disfavored child of Ozai).
She also did what she genuinely thought was best for the Fire Nation. Azula did like to be in control in most situations but she wasn’t after a greater power, like being Fire Lord. She only wanted the throne at the very end because it was all she had left. She no longer had her father, friends, mother, or even Zuko. Azula was terribly unhappy when Ozai gave her the Fire Lord title instead of allowing her to come with him to destroy the Earth Kingdom. As messed up as it is, destroying the Earth Kingdom was Azula’s idea of father-daughter bonding time. At her core, what Azula craved the most was real unconditional love, not power.